Steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. Polythionic acid stress corrosion cracking deterioration. Effect of polythionic acid concentration on stress. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. This standard is directed toward preventing stress corrosion cracking scc caused by polythionic acid pta that can be formed by reaction of oxygen and water with sulfide corrosion products i. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen and water. The terminology sensitization, which is generally used to discuss intergranular corrosion cracking behaviors, has different metallurgical meanings depending on intergranular corrosion test methods such as strauss, electrochemical potentiokinetic reacitivationepr and wackenroeder test. Stress corrosion cracking susceptibility of stainless steels. Polythionic acid stress corrosion cracking pascc in stainless steel is a downtime phenomenon. Cracking of sensitized stainless steels inspectioneering. Effect of carbon content on polythionic acid stress corrosion. Protection of austenitic stainless steels and other. Ctlpolythionic stress corrosion cracking of stainless.
Stress corrosion cracking susceptibility of stainless. Exposure to oxygen and water during turnaround forms polythionic acid and that leads to pta scc on sensitized stainless steel, where soda ash washing, nitrogen purge and pwht is required as a nace countermeasure. However, in some instances, stabilized austenitic sss have been found to be susceptible to pitting, crevice. Rp017097 polythionic stress corrosion cracking protection. Effects of sensitization and service fluid chemistry on. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress. Nacesp0170 protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment nacesp0170 2018 edition current show complete document history. An austenitic stainless steel for sulfuric acid corrosion environments. Results reveal that the stress corrosion life decreases rapidly on increasing the concentration from 0. Failure of 321 stainless steel heater tube in heavy crude oil. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen air and water.
Effect of polythionic acid concentration on stress corrosion. Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment this standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from pta scc that can occur during a shutdown of refinery equipment.
Depletion of cr in steels promotes corrosion adjacent to grain boundaries. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking and component failure 169. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of. Polythionic acid stress corrosion cracking occurs on sensitized stainless heater tubes in hydroprocessing units. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Sp04032015, avoiding caustic stress corrosion cracking of refinery equipment and piping sp01142014sg, refinery injection and process mix points sp0170hd2012sg protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Standard recommended practice austenitic stainless steels.
Polythionic acid stress corrosion cracking in heater pipes. For heaters with stainless steel tubes, an evaluation should be made to determine their susceptibility to internal and external pascc. Complete document protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment view abstract product details detail summary view all details. If deemed necessary, specific steps should be taken to prevent cracking during downtime. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. Abstract polythionic acid stress corrosion cracking pta scc of. Jan 05, 2016 polythionic acid neutralization and decontamination process. Nace rp0170 protection of austenitic stainless steels. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. Nace sp01702018 protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. Nace sp0170 protection of austenitic stainless steels. Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Dtn170 stainless steel protector dtn170 is a mixture of low chloride soda ash, stainless steel stress cracking inhibitor and surfactant when mixed with low chloride water will meet the nace rp017097 standard for protection of austenitic stainless steel from polythionic acid stress corrosion cracking during shutdown of refinery equipment.
The cracks are intergranular and narrow with no significant branching. Based on this analysis the leaks were caused by cracks that initiated on the id surface. Stress corrosion cracking by krittin rattakham youtube. Resistant to chloride and polythionic acid stress corrosion cracking.
A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by. The stress corrosion cracking sco of sensitized type 304 stainless steel in thiosulfate. Nace sp0170 protection of austenitic stainless steels and. All of the cracks observed were found underneath the coke deposits. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Methods to protect austenitic stainless steel and other austenitic alloys from polythionic acid stress corrosion cracking scc occurring during downtimes and. Polythionic acid stress corrosion cracking of type 310 stainless steel. Stress corrosion cracking issues in syngas plants that may be. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Stress corrosion cracking issues in syngas plants that may. Why does chloride stress corrosion cracking and pascc only. In the presence of sulfide corrosion products, such conditions are met during shutdown, when moisture originates from general humidity, washing or steam out and oxygen as air enters the unit upon opening to atmosphere.
Whereas 9cr is immune to scc, chlorides in the presence of water may cause scc of any 300 ss piping at temperatures above about 140. What are the industrial practices being followed in. Rp017097 polythionic stress corrosion cracking protection free download as pdf file. For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. The terminology sensitization, which is generally used to discuss intergranular corrosioncracking behaviors, has different metallurgical meanings depending on intergranular corrosion test methods such as strauss, electrochemical potentiokinetic reacitivationepr and wackenroeder test. Standard recommended practice austenitic stainless steels and. Nace rp0170 protection of austenitic stainless steels and. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. Pta scc is also covered by nace standard rp017097, protection of. Results show that alloys 304 and 304l, in the solution. Unless suitable precautions are taken, in accordance with nace rp0170 nace, 1997. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. These characteristics are consistent with stress corrosion cracking due to polythionic acids.
Chemical studies of polythionic acid stresscorrosion cracking. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Nacesp0170 protection of austenitic stainless steels. Polythionic acid neutralization and decontamination process. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. Overview of polythionic acid stress corrosion cracking pascc. Stress corrosion tests using ubend specimens were carried out in samans solutions containing polythionic acid concentrations from 0. Subsequently, this particular form of intergranular scc was called polythionic acid stress corrosion cracking pascc. Sulfur can come from feed stock, additives or fuels. Stress corrosion cracking of gas pipelines 3 minute 2014 thesis finalist duration. Stress corrosion cracking scc may be defined as the delayed failure of alloys by.
Pdf polythionic acid corrosion in refinery hydroprocessors. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist. Stress corrosion cracking scc caused by polythionic acid andor chlorides has occurred in coal liquefaction pilot plants. The item was exposed to sulfur containing natural gas in a continuous flare. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Stresscorrosion cracking of sensitized type 304 steel in low temperature borated water has been observed.
Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. Polythionic stress corrosion cracking of stainless steel tube. Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. Dec 12, 2012 in the form of stress corrosion cracking scc from chlorides, and potentially from polythionic acids, that would not occur with 9cr. Stabilized austenitic stainless steels sss have since been widely used in the petroleum refining industry because of their resistance to sulphidic corrosion and polythionic acid stress corrosion cracking scc, as well as of their excellent strength and toughness.
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